why this is true?

Question

(True > False) == False is false.
True > (False == False) is false.

why True > False == False is true?

Answer 1

True value is 1, False value is 0

1>0 == false
// false.

Answer 2

My understanding for the last line is that when Python lets you combine comparison operators like that (WITHOUT using parentheses to make precedence explicit), it's a kind of syntactic sugar.

So in Python something like:
x > y == z
really means:
x > y and y == z
but the first saves you some typing.

And like Nahuel said, True and False behave like 1 and 0. So:
>>> print(True > False == False)
output: True
is because:
>>> print(True > False and False == False)
output: True

As an aside, the one exception to 1 and 0 for True and False is when you convert them to strings.
>>> str(True)
output: 'True'